Chemical-thermal treatment and surface hardening of steel

In order to increase the strength and hardness of materials, they are subjected to heat treatment: they are heated and kept in a thermal oven and cooled. But this method is not always suitable. In particular, it is not used for metals such as copper and aluminum.

Then cold hardening is used - a technological treatment that involves changing the shape of the product through cold plastic deformation. At the same time, the hardness and strength of the material increases, but its ductility - the ability to deform without destruction - decreases.

Cold hardening and cold hardening

For some alloys, cold hardening is the only possible way to increase strength. Such alloys, for example, include corrosion-resistant alloys of chromium and nickel.

The study of a process such as cold hardening (hardening of metal) is one of the important and interesting problems of materials science. For example, as a result of cold hardening, the hardness of the surface layers of steel increases several times.

The terms cold hardening and cold hardening are often considered almost synonymous, meaning:

  • the process of changing the structure of the material;
  • increasing its hardness and strength as a result of these changes.

But in some literary sources these terms are distinguished: cold hardening is a process that can be either spontaneous or purposeful, while cold hardening is a deliberate process, the purpose of which is to strengthen the metal.

From this point of view, cold hardening can be a process both useful and harmful, and cold hardening is a process that can only be useful.

As the temperature increases, the cold hardening ability decreases noticeably. For example, cold hardening of aluminum is impossible at temperatures above 200 °C. This temperature (recrystallization temperature) will be different for different substances. For low-melting metals (including zinc, lead, tin), the recrystallization temperature can be negative.

Process description

Let us consider the essence of the phenomenon of cold hardening. As is known, almost all metals and their alloys (for example, aluminum or copper and their alloys) have an ordered crystalline structure. But it's not that simple. They consist of grains, within which the arrangement of atoms is ordered. But the grains themselves are located chaotically in relation to each other, that is, disordered.

Under mechanical load, dislocations (microscopic defects) appear in the structure of the substance. As the load increases, dislocations move and interact with each other.

Another structure is formed. It resists the deformation that remains after the load is removed (plastic deformation). The ability of the metal to resist deformation increases.

But it should be borne in mind that with cold hardening, the plastic properties of the material become worse. For example, the ductility of low-carbon steel decreases by 5-6 times. The resistance to plastic deformation also decreases when its sign changes (the so-called Bauschinger effect).

After hardening, the state of the substance is thermodynamically unstable. If ductility needs to be increased, hardening is removed by recrystallization annealing, heating the material above the recrystallization temperature. In this case, the material goes into a more stable state. The need to remove hardening arises, for example, in metallurgy during the production of wire or tape.


The dislocation density increases during work hardening, which leads to a decrease in bulk density. In this case, the metal grains are stretched in the direction of the forces that act on them. This grain orientation is called deformation texture. Due to texture, anisotropy of the mechanical properties of metals and alloys occurs.

The following conclusions can be drawn:

  • after cold hardening or hardening, the hardness and strength of the material increases;
  • The fragility of the material also increases.

In particular, cold hardening of steel is relevant for products in which it is necessary to prevent surface cracking and such phenomena as metal fatigue, which leads to the accumulation of internal stresses, the occurrence of cracks, and ultimately to the destruction of the material.

Types of hardening

Basically, there are two types of cold hardening:

  • phase, when changes in the crystal lattice are caused by phase changes;
  • deformation, when lattice changes are caused by external forces.

The formation of deformation hardening occurs when the surface being treated is exposed to balls or a stream of pellets.

Hardening equipment

Equipment for the process of cold hardening of aluminum and other metals and alloys is quite diverse. In industry, cold hardening is a fully automated process that is performed on electronically controlled devices.

In particular, when deformation hardening is formed, the number and feed rate of pellets is automatically adjusted.

Application

In industry, cold hardening is used to impart strength to products made of stainless steel, copper, aluminum and its alloys. This is very important for mechanical engineering, since various components and mechanisms often operate in unfavorable conditions and wear out over time.

What product characteristics are affected by hardness?

Specific criteria and indicators are important for each area. For example, wear resistance , which is the susceptibility of a metal to abrasion, surface destruction, and change in size during operation under certain conditions, is absolutely important in every area of ​​use of this material. It is impossible to find an area where this indicator would not be just important, but even paramount, be it a children's construction set or a new viaduct, a surgical needle or a communications tower, a gas pipe or a wedding ring. Naturally, the higher the wear resistance, the longer the product will last, and the more expensive it will cost.

The next thing that hardness directly affects is the ability to process a particular metal or alloy and the type of processing. Here we can distinguish several large groups of processing methods:

  • mechanical,
  • casting,
  • thermal,
  • pressure,
  • welding,
  • electric,
  • chemical

Of course, when choosing a method, several criteria must be taken into account (the main ones are the initial properties of the metal and the desired result), but the hardness of the starting material is one of the fundamental ones in this matter.

The hardness of metals also affects resistance to pressure and other forces. This is important, for example, for shafts or bearings that are subject to centrifugal and frictional forces.

The hardness of the material determines the possibility of using the product as a tool for working with other metal or non-metal products. Here we are talking about tool steel with a high carbon content (from 0.7% and above). Various tools are made from it for both industrial and home use: drills, cutters, hammers, pliers, files, surgical scissors, scalpels, etc.

The natural conclusion from all of the above is the recognition of the enormous importance of the hardness indicator of metals and the question of the likelihood of its increase.

!!! It is important to keep in mind that a certain hardness is expected for a certain product. There is no such thing as “the harder, the better.” Products with very high hardness are difficult to process and at the same time become brittle.

For example, the higher the hardness of the knife, the longer it will remain sharp, but problems with sharpening may arise, and with frequent use the blade will crumble and break.

Knives with a hardness below 60 HRC will serve a hunter or tourist for a long time, because... They are quite reliable: they withstand shock loads well, do not deform greatly, are resistant to corrosion, and are easy to sharpen.

Technology of cold hardening and cold hardening of metal

Hardening is a phenomenon in which the strength and hardness of a metal product increases. Changes in properties are achieved through plastic deformation. Metal hardening occurs at a high temperature, the value of which is not sufficient for recrystallization of the workpiece. This phenomenon can be both harmful and beneficial.

Hardening is a technological process that pursues the same goals as cold hardening. The main difference is that the latter phenomenon can occur as a result of conscious or unconscious actions.

For example, during machining by cutting with high speed and cutting depth, the surface acquires excess strength, which increases the fragility of the product. Cold hardening is only useful strain hardening, the use of which is deliberate.

The essence and purpose of cold hardening and cold hardening

As a result of plastic deformation, changes occur in the crystal lattice and phase composition of the material. The process of cold hardening of metal is accompanied by the formation of defects in the internal structure of the product. In this case, the properties of the material change as follows:

  • resistance to mechanical damage increases (metal strengthening);
  • the hardness of the material increases;
  • resistance to dynamic loads is reduced;
  • plasticity is lost;
  • there is a decrease in resistance to plastic deformation with the opposite sign - this is called the Bauschinger effect.

Thus, the yield strength of the metal is reduced. This parameter determines the maximum stress on the product at which it will begin to deform plastically. If the degree of load does not exceed the permissible value, after the cessation of external forces, the metal will return to its previous state.

This parameter is especially important for cold-worked steel, which is used as the main material in load-bearing structures of various buildings and structures. The project is drawn up taking into account the maximum loads on individual elements and the object as a whole.

The study of the metal structure suggests that after exceeding the yield strength, the product receives strain hardening. To harden the surface by cold hardening, special equipment is used, which will be discussed below.

When exposed to steel and other ferromagnetic materials, an increase in the magnetic field strength is observed. This parameter is called coercive force. At the same time, the magnetic permeability of the product decreases.

The phenomenon under consideration helps to improve the performance properties of ductile metals. When cold-working aluminum and alloys based on it, a significant increase in hardness and increase in yield strength are observed.

The convenience of working with ductile metals lies in the fact that for cold deformation processing you can use any of the following methods:

  • rolling;
  • deep drawing;
  • forging;
  • flange.

In what cases is cold hardening used, and when is cold hardening used?

The physics of these processes is based on strain hardening of a metal product. The difference is this:

  1. Hardening is any strain hardening of metal, the effect of which can be both positive and negative.
  2. Hardening is considered only a process that is deliberately applied to a product in order to improve performance characteristics.

Technical documentation, including state standards, ANSI and ISO, does not contain the term peening. For example, deformation-hardened aluminum is called cold-worked aluminum. For this metal, the degree of processing is indicated by the letter H. It is followed by a numerical definition, which can contain from one to three digits.

Types of hardening

Strain hardening of metal is classified according to the processes that are activated in the workpiece during the formation of the work-hardened layer.

In the case of the formation of new phases that differ in a different specific volume, the phenomenon is called phase. If the cause of the changes is the action of external forces, hardening is called deformation hardening.

There are two categories:

  1. Centrifugal ball. The product is affected by balls that are located in the rim sockets of the installation. Its operating principle is based on rotation, when, under the influence of centrifugal force, the elements exert a mechanical effect on the workpiece being processed.
  2. Shot blaster. This method is based on the use of kinetic energy. Shots with a diameter of up to 4 mm, made of durable material: cast iron, steel or ceramics, are used as processing elements. According to technological requirements, the flow speed can reach 70 m/s.

Technology of hardening and hardening of metal, tape, in Russia | MetalEnergoHolding

In the metal rolling industry, cold hardening or strain hardening is a controlled technological process that is used to increase the hardness of metals and increase their strength characteristics.

This technology is applied to those materials that cannot be refined by heat treatment. Hardening is not used to change the mechanical properties of rolled products made of copper, aluminum alloys, low-carbon steels, and chromium-nickel alloys.

For such materials, strain hardening is the only way to increase strength characteristics.

The definitions cold hardening and cold hardening are used to denote the process of changing the structure of the metal, as well as increasing its hardness as a result of external influence. At the same time, the concept of hardening includes both natural processes occurring in the structure of the metal and those controlled by special processing methods.

According to its origin, cold hardening can be:

  • Phase. In this case, structural changes are caused by phase changes that occur as a result of heat treatment of the metal.
  • Deformation. Strengthening and increasing hardness occurs as a result of the influence of external forces.

In particular, phase hardening (undesirable) occurs when cutting alloys that have ductility and softness. Too deep a cut with a large thickness of the workpiece, made at high speed, causes intense hardening, a decrease in the ductility of the metal, and an increase in fragility.

Unlike cold hardening, cold hardening is a controlled process. Hardening is not always beneficial. When hardening occurs, the plastic properties of materials decrease. For example, the ductility of low-carbon steel alloys is reduced by more than 5 times. At the same time, there is a decrease in the resistance of the metal to mechanical stress - tensile, tensile, compressive and bending loads.

How are carbon steels classified by quality?

Based on carbon content, high-quality carbon steels are divided into: low-carbon (up to 0.25% C), medium-carbon (0.3-0.55% C) and high-carbon (0.6-0.85% C).

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