U12 steel for knives: pros and cons. X12MF steel for knives: pros and cons


Description

U12 steel is used : for the manufacture of hand taps, files, metal scrapers; parts of cold stamping dies of cut and die cut small sizes and without cross-sectional transitions; cold heading punches and small dies; calibers of simple shape and lower accuracy classes; tools with reduced wear resistance at moderate and significant specific pressures (without heating the cutting edge): files, razor blades and knives, sharp surgical instruments, scrapers, engraving tools.

U12 steel for knives: pros and cons. X12MF steel for knives: pros and cons

Let us say right away that there is no ideal steel that would meet all desires. You always have to look for some “golden mean” in order to select a metal composition that would be ideal for specific purposes. A simple example is that if a knife is made of “soft” steel, then it is easy to sharpen. But on the other hand, such blades will dull much faster. Household knives that we use every day in the kitchen are often made from this type of steel.

Another example is that products made from “hard” steel last much longer. But they also have their drawbacks - when they hit a hard object, chips can form. And in general, there is a golden rule for making knives: the more complex the steel composition, the more different impurities used in production, the more expensive the final price will be. A striking example is blades made of Damascus steel. They are close in their properties to the standard, but their cost is an order of magnitude higher. And you definitely won’t use such knives in the kitchen.

In addition to the steel grade itself, the heat treatment process is of great importance. It is at this stage of production that a mistake can be made, which will subsequently negatively affect the product itself. It can rust quickly, be too soft, become dull quickly, or even break down. But this is not all about “Zlatoust knives”. Our product is of high quality. And any blade that bears our mark meets the most advanced world standards.

Now we’ll tell you in more detail what grades of steel our knives are made from. We will also tell you in detail how this or that chemical composition differs, and what its main advantages are.

Steel grades:

65G-H12MF1

One of the best examples of steel in existence. Its main advantage is that it cuts perfectly, does not dull for a long time and can even withstand serious shock loads. This steel is easy to care for - just polish, sharpen, and does not require any special storage conditions. But you need to carefully monitor the environment in which the blade will be kept. It is recommended to avoid alkaline and acidic environments. Otherwise, the knife will very quickly begin to lose its properties and appearance. For example, with short-term exposure to negative factors, dark spots will begin to appear on the metal. And constant maintenance in an alkaline environment will lead to rust.

U10A-7HNM

This steel and others like it (marked “U7” and “U8”) are classified as high-hardness metals. Such materials are often used to make various tools, such as files. It is these that are most often then forged into blades. In this case, original knives are obtained, on which specific notches are preserved, they turn into an original decorative element. Knives made from this steel cut well and stay sharp for a long time. But they have their own drawback - too weak resistance to corrosion. Without constant treatment, such blades quickly begin to lose their original appearance - the steel darkens, and then rust may appear.

40Х13-Х12Ф1

This is one of the most popular steel grades. Used in almost all areas. Such knives can be found in the kitchen of a good housewife; they are sold in souvenir shops. They are also used by fishermen, divers and divers. And this is where their main advantage becomes clear - high resistance to corrosion. They do not deteriorate even with prolonged exposure to moisture. And they last for a very long time. Steel also cuts well and does not require any special care. But there are also certain disadvantages. For example, this metal is practically impossible to harden. And besides, it is “soft” steel, that is, it is easy to sharpen, but the knives quickly become dull. So you will have to constantly monitor the quality of the blade.

Standards

NameCodeStandards
Sheets and stripsB23GOST 103-2006
Long and shaped rolled productsB22GOST 1133-71, GOST 2590-2006, GOST 2591-2006, GOST 2879-2006
Long and shaped rolled productsB32GOST 1435-99, GOST 5210-95, GOST 7417-75, GOST 8559-75, GOST 8560-78, GOST 14955-77, TU 14-11-245-88, TU 14-1-1271-75
Sheets and stripsB33GOST 4405-75
Medium and high carbon steel wireB72GOST 5468-88, GOST 9389-75

Chemical composition

StandardCSPMnCrSiNiFeCu
GOST 1435-991.1-1.29≤0.028≤0.030.17-0.33≤0.20.17-0.33≤0.25Remainder≤0.25

Fe is the basis. According to GOST 1435-99, the mass fraction of chromium, nickel and copper is indicated for group 1 of metal products. The mass fraction of sulfur in steel produced by electroslag remelting should not exceed 0.013%. In metal products of the 3rd group, the mass fraction of Cr ≤ 0.20-0.40%, Ni ≤ 0.25%, Cu ≤0.25%. In metal products of the 1st and 3rd groups, made from steel obtained by the scrap process, the mass fractions of nickel, copper and chromium increased by 0.05% of each element compared to those indicated in the table are allowed. In metal intended for the production of cold-rolled strip, an increase in the mass fraction of nickel, copper and chromium is not allowed.

Mechanical characteristics

Section, mmholiday t, °CsТ|s0.2, MPaσB, MPad5, %d4y, %kJ/m2, kJ/m2H.R.C.
Annealed cold-rolled strip of the highest quality category
0.08-3≤750≥10
Samples with a cross section of 21-30 mm. Quenching in water from 810-830 °C + Tempering
400≥1370≥1570≥9≥24≥200≥52
A sample with a diameter of 5 mm and a length of 25 mm, deformed and annealed. Deformation speed 10 mm/min. Strain rate 0.007 1/s
≥105≥60≥68
Samples with a cross section of 21-30 mm. Quenching in water from 810-830 °C + Tempering
500≥880≥1040≥11≥30≥290≥40
Long products. Annealing
≥325590-690≥28≥50≥270
A sample with a diameter of 5 mm and a length of 25 mm, deformed and annealed. Deformation speed 10 mm/min. Strain rate 0.007 1/s
≥100≥52≥96
Samples with a cross section of 21-30 mm. Quenching in water from 810-830 °C + Tempering
600≥650≥760≥18≥52≥440≥26
A sample with a diameter of 5 mm and a length of 25 mm, deformed and annealed. Deformation speed 10 mm/min. Strain rate 0.007 1/s
≥60≥40≥100
≥34≥65≥100
≥18≥74≥100
≥15≥92≥100
Long products. Annealing (at 20 °C НВ=207)
≥325590-690≥2845-55
≥320≥570≥23≥47
≥310≥450≥41≥60
≥110≥140≥56≥74
≥59≥76≥56≥82
≥53≥72≥59≥85
≥34≥40≥52≥91
≥20≥28≥55≥98

Steel U12, U12A carbon tool

Decoding

  • According to GOST 1435-99, the letter U in the designation of the steel grade means that the steel is carbon.
  • The number 12 following the letter Y indicates the average mass fraction of carbon in tenths of a percent, i.e. The average carbon content in steel 12 is about 1.2%
  • The presence of the letter A at the end of the marking means that the steel is high quality, i.e. with increased requirements for the chemical composition.

Substitute

Steels U10A, U11A, U10, U11.

Foreign analogues [1]

steel gradeStandard
N12 (Poland)PN/H 85020
N 12 E (Poland)PN/H 85020
S122 (Hungary)MSZ 4354
U12 (Bulgaria)BDS 6751
I 12 A (Bulgaria)BDS 6751 (83)
SK2 (Japan)JIS G4401 (83)
19221 (Czech Republic/Slovakia)CSN 419221
BW1C (UK)BS 4659 (89)
C120 KU (Italy)UNI 2955-82 Part 2
C 120E3U (France)AFNOR NF NF A 35-590 (92)
C 120 (Spain)UNE 36071 (75)

Type of delivery

  • Long products, including shaped steel: GOST 1435-90, GOST 2590-88, GOST 2591-88, GOST 2879-88.
  • Calibrated rod GOST 1435-90, GOST 7417-75, GOST 8559-75, GOST 8560-78.
  • Polished rod and silver steel GOST 1435-90, GOST 14955-77. Tape GOST 2283-79, GOST 21997-76.
  • Strip GOST 4405-75, GOST 103-76.
  • Forgings and forged blanks GOST 1435-90, GOST 4405-75, GOST 1133-71.

Characteristics and Application

Tool steel U12 (U12A) belongs to the group of steels with reduced hardenability. Steels of this group must be hardened in water, and tools made of this steel, as a rule, have an unhardened core. Quenching in water requires measures to be taken against severe warping, i.e. When designing a tool, sharp corners and sharp transitions of sections should be avoided [2].

Experience shows that the hardenability of steel U12 and U12A is very variable. Individual melts of the same brand can be calcined to different depths [3].

When choosing this grade of steel, you should keep in mind that the higher the hardness (for example, more carbon, lower tempering), the higher the wear resistance, but the lower the strength. Therefore, if the operation of the tool is not accompanied by shock loads, the blade edge has a sufficient cross-section - it is desirable to have a high hardness (62 HRC and above) and, therefore, high-carbon steel U12 should be used and a low tempering should be given (150-200 ° C), otherwise steels with lower carbon content are used, for example U7-U8, after tempering at 250-300 °C and ˂60 HRC [3]xxxxxxxxx.

U12 steel is used for the manufacture of tools with maximum wear resistance and the highest hardness, for example:

  • incisors,
  • various metal-cutting and measuring tools,
  • files,
  • chisels for cutting files,
  • engraving tool,
  • drawing boards, etc.

Cutting tools operating in conditions that do not cause heating of the cutting edge:

  • hand taps,
  • small-sized machine taps,
  • dies for grains,
  • small-sized reamers,
  • needle files,
  • measuring instrument of simple form: smooth gauges, staples,
  • stands for cold grinding of edged and notched small sizes and without cross-sectional transitions,
  • cold heading dies and small sized stamps,
  • calibers of simple shape and lower accuracy classes.

Chemical composition, % (GOST 1435-99)

steel gradeMass fraction of element, %
carbonsiliconmanganesesulfurphosphorus
no more
U121,10-1,290,17-0,330,17-0,330,0280,030
U12A1,10-1,290,17-0,330,17-0,280,0180,025

Phase composition, % by mass

FerriteCarbidesCarbide type
81-83,518,5-17Fe3C

Temperature of critical points, °C [2]

Ac1Ac3Ar1Mn
730820700200

Hardening [3]

The hardening temperature of hypereutectoid steel U12A lies in the range between Ac3 and Ac1. The structure of steel in the hardened state consists of martensite and excess (secondary) carbides. The optimal hardening temperature is 790 °C.

In hardened steel, the tetragonality of martensite and internal stresses create significant brittleness, so tempering after hardening is a mandatory operation. [3]

Recommended hardening modes [4]

OptionTemperature, °CCoolingCooling down to 20°CH.R.C.Structure or score of martensite on scale No. 3 GOST 8233-56
WednesdayTemperature, °CExcerpt
I770-790Water20-40Up to 200-250 °CIn oil62-641
II5% aqueous solution of table salt62-65
III5-10% aqueous alkali solution62 — 64
IV790 — 810Industrial oil 12Up to 20 - 40 °C62-641-3 For products with a diameter or thickness of less than 6-8 mm
40 — 50Sorbitol-troostite Depending on the diameter or thickness of the product
V790-810Melt of saltpeter, alkali150 — 180Exposure in the melt is equal to exposure during heating for quenchingOn air62-641-3 For products with a diameter or thickness of less than 6-8 mm
VIThe melt temperature and duration of isothermal exposure are selected according to the diagram in Fig. 1, depending on the required hardness. Cooling to 20 °C in air Sorbitol-troostite

NOTES:

  • It is recommended to calculate the duration of exposure during heating for hardening according to the All-Russian Scientific Research Institute method [5].
  • Option III is used to prevent the formation of soft spots during hardening.
  • When adding 4 - 6% water to the alkali melt, option V is used for products with diameters or thicknesses up to 10-12 mm.

Cold treatment [4]

Hardening optionCooling temperature, °CPurposeHardness increase ΔHRC
IV-50Dimensional stabilization of high precision tools1-2

NOTE. Cold treatment should be carried out no later than 1 hour after hardening.

Recommended holiday modes [4]

OptionVacation appointmentHeating temperature, °CHeating mediumH.R.C.
IRelieving stress, stabilizing structure and dimensions140-160Oil, molten saltpeter, alkali62-64
160-18061-63
180-20060 — 62
200-25056-61
IIRelieving stress and reducing hardnessSee note 2Melt saltpeter, alkali, air atmosphere furnace

NOTE:

  1. High precision products (1-2 microns) after preliminary grinding are subjected to repeated tempering (aging).
  2. The tempering mode to obtain a hardness below HRC 56 is selected according to a schedule in accordance with the required hardness.
  3. Tempering at temperatures above 250 C ensures stabilization of product dimensions.
  4. For heating rates and holding time during tempering, see table. 3 Applications.

Tempering temperature of various tools made of U12 steel [3]

Types of toolsSteelTemperature, °CAcceptance hardness of the working part HRC
TapsU12180-20060-62
SweepsU12160-18062-64

Hardness of carbon steel U12 after tempering [7]

steel gradeAkalka modeHardness after quenching HRCHardness HRC after tempering at temperature in °C
temperature in °Ccooling medium200300400500600
U12770-790Through water to oil62-6461-6354-5848-52

Approximate heat treatment temperature and hardness of U10 steel in the annealed state [6]

Annealing temperature °CHardness after annealing HB (no more)Quenching temperature °C
760-780 °C207760-790 °C

Technological process of isothermal annealing of steel U12, U12A [6]

steel gradeFirst heatingIsothermal holdingHardness HB
Temperature, °CExposure per hourTemperature, °CExposure per hour
U12, U12A750-7701,5-2,5640-6801-2187-207

Recrystallization annealing temperature of steel [7]

Pressure treatment followed by annealingsteel gradeAnnealing temperature in °C
Cold drawing (calibration) of barsU12700

Approximate annealing modes for tool steels U12, U12A to improve machinability during cutting [7]

Heating temperature in °CCoolingIndentation diameter according to Brinell in mm
760-780With an oven at 50° per hour to a temperature of 500°C, and then in air≥4,2

NOTE. To improve the machinability of tool steels, high tempering at a temperature of 650-680 °C is also used.

Hardness [4]

Without °CannealingAfter °C annealingAfter °C hardening
dotp, mmNVdotp, mmNVQuenching temperature °C, °C, °C and cooling mediumH.R.C.
3,7-3,3269-341≥4,2≤207760-780, water≥62

Mechanical properties depending on tempering temperature [8]

tref., °Cσ0.2, MPaσв, MPaδ5, %ψ, %KSU, J/cm2Hardness HRCе
400137015709242052
500880104011302940
60065076018524426

NOTE. Samples size 32x32x42 mm. Hardening from 760-790 °C.

Steel hardness depending on tempering temperature [8]

tref., °CHardness HRCе
160-18062-64
180-22059-63
200-27055-61
450-50037-47

NOTE. Samples with a cross section of 21-30 mm. Quenching from 810-830 °C in water.

Mechanical properties depending on test temperature

tsp., °Cσ0.2, MPaσв, MPaδ5, %ψ, %KSU, J/cm2
Annealing at 20 °C; hardness HB 207 [4, 9]
20325590-6902845-5527
200570234773
400310450416069
600110140567462
70059765682356
80053725985323
90034405291225
100020285598157
A sample with a diameter of 5 mm and a length of 25 mm, °C, deformed and annealed. Deformation speed 10 mm/min; °C strain rate 0.007 1/s [10]
7001056068
8001005296
9006040100
10003465100
11001874100
12001592100

True generalized mechanical properties of annealed steel at 20 °C [4]

StretchingCompressionTorsion
sk, kgf/mm2q, %sszh, kgf/mm2q, %tk, kgf/mm2q, %
50-60100-11050-60150-16050-6085-95
  • sk—true tensile strength
  • sсж - true compression resistance
  • q, % - true shift
  • τk - true torsional strength

NOTE. For all types of deformation, fracture is ductile.

Technological properties [10]

  • Forging temperature, °C: beginning 1100, end 750. Slow cooling in air.
  • Weldability - not applicable to welded structures. Welding method - KTS.
  • Cutting ability - Kv tv.alloy. = 1.0 and Kv σ.st = 0.9 in the annealed state at HB 207.
  • Tendency to temper brittleness - not prone.
  • Flock sensitivity - not sensitive.

Heat resistance [10]

Temperature, °CTime, hHardness HRCе
150-160163
200-220159

Hardenability [9, 11]

Heat treatmentCritical hardness HRCеCritical diameter, mm, after hardening
in waterIn oil
Hardening6110-204-6
Hardening from 760 °C42-6620

NOTE. Sandability is good.

Physical properties at 20 °C [12]

Heat treatmentHc, A/cmμmax x 10-6, G/m4πJs, Tρ, Ohm*mm2/mγ, g/cm3
Annealing6-8*851,97,81
Hardening from 780-810 °C41-5011-12,50,7-0,81,7-1,8
Hardening from 780-810 °C, tempering at 150-200 °C40-3214-17,50,75-0,81,75-1,85
  • Hc—coercive force;
  • μmax—maximum magnetic permeability;
  • 4πJs—magnetic saturation;
  • ρ—resistivity;
  • γ—density;

*The lower limit of Hc values ​​corresponds to the structure of granular perlite, the upper limit - to lamellar perlite.

Linear expansion coefficient α*106, K-1

steel gradeα*106, K-1 at test temperature, °C
20-10020-20020-30020-40020-50020-60020-70020-80020-90020-1000
U12, U12A10,511,812,613,414,114.815.315,016,316,8

Thermal conductivity coefficient λ W/(m*K)

Steel gradeλ W/(m*K), at test temperature, °C
20100200300400500600700800900
U12, U12A454340373532282425

Specific heat capacity c, J/(kg*K)

steel grades, J/(kg*K), at test temperature, °C
20-10020-20020-30020-40020-50020-60020-70020-80020-90020-1000
U12, U12A469503519536553720611712703699

Young's modulus (normal elasticity) E, GPa

Steel gradeAt test temperature, °C
20100200300400500600
U12209205200193185178166
U12A209205200193185178166

Modulus of elasticity in torsional shear G, GPa

steel gradeAt test temperature, °C
20100200300400500600
U12, U12A82807875726963

Bibliography

  1. Shishkov M.M. Brand of steels and alloys. 2000
  2. Poznyak L.A. Tool steels: Directory. -M.: Metallurgy. 1977
  3. Gulyaev A.P. Metallurgy. 1977
  4. Gulyaev A.P. Tool steels. Directory. 1975
  5. Smolnikov E.A. How to calculate heating time during hardening. “Metal science and heat treatment of metals.” 1970 No. 12
  6. Kamenichny I.S. Practice of heat treatment of tools. 1952
  7. Filinov S.A., Firger I.V. Thermist's Handbook. 1969
  8. Tylkin M.A. Strength and wear resistance of metallurgical equipment parts. 1965
  9. Brand of steel and alloys, 3rd ed. Ed. Kryanina I.R. 1977
  10. Brand of steel and alloys. Ed. Sorokina V.G. 1989
  11. Brand of steels. - M.: CBTI, 1961.
  12. Brand of steel for mechanical engineering. NIIMASH. 1965

Find out more

Alloyed tool steel 9ХС…

High-speed tool steel…

Structural carbon steel of ordinary grade...

HVG alloy tool steel…

Description of mechanical symbols

NameDescription
SectionSection
sT|s0.2Yield strength or proportional limit with tolerance for permanent deformation - 0.2%
σBShort-term strength limit
d5Elongation after break
d4Elongation after break
yRelative narrowing
kJ/m2Impact strength
H.R.C.Rockwell hardness (diamond indenter, spheroconic)

Steel grade A12 – Metallurgical company

Brief designations:
σв— temporary tensile strength (tensile strength), MPaε— relative settlement at the appearance of the first crack, %
σ0.05— elastic limit, MPa— ultimate torsional strength, maximum shear stress, MPa
σ0.2— conditional yield strength, MPaσben— ultimate bending strength, MPa
δ5 , δ4 , δ10— relative elongation after rupture, %σ-1— endurance limit during bending test with a symmetrical loading cycle, MPa
σсж0.05 and σсж— compressive yield strength, MPaJ-1— endurance limit during torsion testing with a symmetrical loading cycle, MPa
ν— relative shift, %n— number of loading cycles
— short-term strength limit, MPaR and ρ— electrical resistivity, Ohm m
ψ— relative narrowing, %E— normal modulus of elasticity, GPa
KCU and KCV— impact strength, determined on a sample with concentrators of the types U and V, respectively, J/cm 2T— temperature at which properties were obtained, degrees
sT— proportionality limit (yield strength for permanent deformation), MPal and λ— coefficient of thermal conductivity (thermal properties of the material), W/(m °C)
HB— Brinell hardnessC- specific heatHotStyle of the material (range 20 o - T), [J/(kg deg)]
H.V.— Vickers hardnesspn and r- density kg/m 3
HRСе— Rockwell hardness, scale CA— coefficient of thermal (linear) expansion (range 20 o - T), 1/°С
HRB— Rockwell hardness, scale Bσ t T— long-term strength limit, MPa
HSD- Shore hardnessG— modulus of elasticity during torsional shear, GPa

physical characteristics

TemperatureE, GPaG, GPar, kg/m3l, W/(m °С)R, NOM ma, 10-6 1/°СC, J/(kg °C)
0209827830
202097830
10020580780945252105469
20020078778143333118503
30019375774940430126519
40018572771337540134536
50017869767535665141553
60016663763432802148720
700759228964153611
800756524115215712
9007489251196163703
1000163703
1200168699

Technological properties

NameMeaning
Weldabilitynot applicable to welded structures. Welding method - KTS.
Tendency to temper brittlenessnot inclined
Forging temperatureStart - 1100 °C, end - 750 °C. Cooling is slow in air.
Flock sensitivitynot sensitive
MachinabilityIn the annealed state at HB 207 Kn tv.all.=1.0 Kn b.st.=0.9
Sandabilitygood

Brand: steel, metal U12

Brand: U12

Brand:U12
Substitute:U10, U11
Classification:Carbon tool steel
Application:cutting tools working in conditions that do not cause heating of the cutting edge: hand taps, small-sized machine taps, dies for grains, small-sized reamers, needle files, simple-shaped measuring tools: smooth gauges, staples.
Foreign analogues:
CSiMnNiSPCrCu
1.1 – 1.290.17 – 0.330.17 – 0.33up to 0.25up to 0.028up to 0.03up to 0.2up to 0.25

Ac1 = 730, Ac3(Acm) = 820, Ar1 = 700, Mn = 200

Weldability:not applicable to welded structures.
Flock Sensitivity:not sensitive.
Tendency to temper brittleness:not inclined.
AssortmentSizeEg.sTd5yKCUThermal change
mmMPaMPa%%kJ/m2
The tape is annealed.0.08 – 375010
Steel590-6903252850270Annealing
Hardness U12 after annealing, GOST 1435-99HB 10 -1 = 217 MPa
TE 10- 5a 10 6lrCR 10 9
hailMPa1/GradW/(m deg)kg/m3J/(kg deg)Ohm m
202.097830
1002.0510.5457809469252
200211.8437781503333
3001.9312.6407749519430
4001.8513.4377713536540
5001.7813.1357675553665
6001.6614.8327634720802
70015.3287592611964
800152475657121152
90016.32574897031196
100016.8699
TE 10- 5a 10 6lrCR 10 9

Foreign analogues of the material

Both exact and closest analogues are indicated!

USAGermanyJapanFranceEnglandEuropean UnionItalyChinaBulgariaHungaryPolandCzechAustria
DIN,WNrJISAFNORB.S.ENUNIG.B.BDSMSZPNCSNONORM
– Short-term strength limit, [MPa]
sT– Proportional limit (yield strength for permanent deformation), [MPa]
d5– Elongation at break, [%]
y– Relative narrowing, [%]
KCU– Impact strength, [kJ/m2]
HB– Brinell hardness, [MPa]
Physical properties:
T– Temperature at which these properties were obtained, [Deg]
E– Modulus of elasticity of the first kind, [MPa]
a– Coefficient of thermal (linear) expansion (range 20o – T), [1/degree]
l– Thermal conductivity coefficient (heat capacity of the material), [W/(m deg)]
r– Material density, [kg/m3]
C– Specific heat capacity of the material (range 20o – T), [J/(kg deg)]
R– Electrical resistivity, [Ohm m]
Weldability:
no limits– welding is performed without heating and without subsequent heat treatment
limited weldability– welding is possible when heated to 100-120 degrees. and subsequent heat treatment
difficult to weld– to obtain high-quality welded joints, additional operations are required: heating to 200-300 degrees. during welding, heat treatment after welding - annealing
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